diff --git a/packages/errors/src/error/error.ts b/packages/errors/src/error/error.ts
index 84429ef..8345fe0 100644
--- a/packages/errors/src/error/error.ts
+++ b/packages/errors/src/error/error.ts
@@ -111,6 +111,18 @@ export const error = <const T extends Record<string, unknown> = Record<string, n
     instance.inherits = inherits ?? undefined;
     instance.stack = stack;
 
+    // Add .from() method for exception chaining
+    instance.from = ( cause: Error ): ErrorInstance<T> => {
+      // Build new causes array: [new cause] + [cause's causes] + [existing causes of instance]
+      // This maintains chronological order: newest first
+      const causeCauses = 'causes' in cause && Array.isArray( cause.causes )
+        ? cause.causes
+        : [];
+      instance.causes = [cause, ...causeCauses, ...instance.causes];
+      instance.cause = cause;
+      return instance;
+    };
+
     // Mark this instance as created by this factory (for is() checks)
     // Use callable to avoid generic parameter conflicts
     ( instance as unknown as Record<typeof FACTORY_SYMBOL, () => unknown> )[FACTORY_SYMBOL] = ErrorFactoryInstance;
diff --git a/packages/errors/src/error/types.ts b/packages/errors/src/error/types.ts
index 086e90e..bd2d5ad 100644
--- a/packages/errors/src/error/types.ts
+++ b/packages/errors/src/error/types.ts
@@ -37,16 +37,28 @@ export type ErrorFactory<TFields extends Record<string, unknown> = Record<string
  * Error instance returned by an ErrorFactory.
  * Contains all standard Error properties plus additional domain-specific fields.
  *
- * Note: Methods like .addNote() and .from() are implemented in separate tasks.
+ * Note: .addNote() is implemented in a separate task.
  */
 export type ErrorInstance<TFields extends Record<string, unknown> = Record<string, never>> =
   ErrorInstanceCore & {
     /** User-defined fields from Standard Schema */
     fields: TFields;
-    // TODO: Implement .addNote() method (Task 05)
+    // TODO: Implement .addNote() method (Task XX)
     /** Additional notes added via .addNote() */
     notes: string[];
-    // TODO: Implement .from() method (Task 06)
+    /**
+     * Chains a cause error to this error.
+     *
+     * @param cause - The error that caused this one
+     * @returns This error instance for chaining
+     *
+     * @example
+     * ```typescript
+     * const err = ValidationError({ field: 'email' })
+     *   .from(new NetworkError('Connection failed'));
+     * ```
+     */
+    from( cause: Error | ErrorInstance ): ErrorInstance<TFields>;
     /** Direct cause of this error (from .from()) */
     cause: Error | null;
     /** Full cause chain from .from() calls */
diff --git a/packages/errors/tests/from.test.ts b/packages/errors/tests/from.test.ts
new file mode 100644
index 0000000..08a855c
--- /dev/null
+++ b/packages/errors/tests/from.test.ts
@@ -0,0 +1,178 @@
+/**
+ * Unit tests for the .from() method.
+ */
+
+import { describe, it, expect } from 'vitest';
+import { error } from '../src/index.js';
+
+describe( '.from() method', () => {
+  describe( 'basic usage', () => {
+    it( 'should set the cause property', () => {
+      const AppError = error( { name: 'AppError' } );
+      const ValidationError = error( { name: 'ValidationError' } );
+
+      const cause = AppError();
+      const instance = ValidationError();
+
+      const result = instance.from( cause );
+
+      expect( instance.cause ).toBe( cause );
+    } );
+
+    it( 'should return the instance for chaining', () => {
+      const AppError = error( { name: 'AppError' } );
+      const instance = AppError();
+
+      const result = instance.from( new Error( 'cause' ) );
+
+      expect( result ).toBe( instance );
+    } );
+
+    it( 'should work with native errors', () => {
+      const AppError = error( { name: 'AppError' } );
+      const instance = AppError();
+
+      instance.from( new TypeError( 'native cause' ) );
+
+      expect( instance.cause ).toBeInstanceOf( TypeError );
+      expect( instance.cause!.message ).toBe( 'native cause' );
+    } );
+  } );
+
+  describe( 'cause chain', () => {
+    it( 'should add cause to causes array', () => {
+      const AppError = error( { name: 'AppError' } );
+      const instance = AppError();
+
+      instance.from( new Error( 'cause' ) );
+
+      expect( instance.causes ).toHaveLength( 1 );
+      expect( instance.causes[0].message ).toBe( 'cause' );
+    } );
+
+    it( 'should preserve nested cause chain', () => {
+      const AppError = error( { name: 'AppError' } );
+      const cause1 = AppError();
+      const cause2 = AppError();
+      cause2.from( cause1 );
+
+      const instance = AppError();
+      instance.from( cause2 );
+
+      expect( instance.causes ).toHaveLength( 2 );
+      // Direct cause is cause2, then cause1 (from cause2's chain)
+      expect( instance.cause ).toBe( cause2 );
+      expect( instance.causes ).toContain( cause1 );
+      expect( instance.causes ).toContain( cause2 );
+    } );
+
+    it( 'should build complete cause chain', () => {
+      const AppError = error( { name: 'AppError' } );
+      const cause1 = AppError();
+      const cause2 = AppError();
+      const cause3 = AppError();
+      cause3.from( cause2 ).from( cause1 );
+
+      const instance = AppError();
+      instance.from( cause3 );
+
+      // causes array contains the full chain: newest first
+      expect( instance.causes ).toHaveLength( 3 );
+      expect( instance.cause ).toBe( cause3 );
+      // Verify all causes are present (order reflects build order)
+      expect( instance.causes ).toContain( cause3 );
+      expect( instance.causes ).toContain( cause2 );
+      expect( instance.causes ).toContain( cause1 );
+    } );
+  } );
+
+  describe( 'method chaining', () => {
+    it( 'should support chaining multiple .from() calls', () => {
+      const AppError = error( { name: 'AppError' } );
+      const instance = AppError();
+
+      const result = instance
+        .from( new Error( 'cause 1' ) )
+        .from( new Error( 'cause 2' ) )
+        .from( new Error( 'cause 3' ) );
+
+      expect( result ).toBe( instance );
+      expect( instance.causes ).toHaveLength( 3 );
+    } );
+
+    it( 'should update cause when chaining', () => {
+      const AppError = error( { name: 'AppError' } );
+      const instance = AppError();
+      const cause1 = new Error( 'cause 1' );
+      const cause2 = new Error( 'cause 2' );
+
+      instance.from( cause1 ).from( cause2 );
+
+      // The direct cause should be the last one
+      expect( instance.cause ).toBe( cause2 );
+      // But causes array should have both
+      expect( instance.causes ).toContain( cause1 );
+      expect( instance.causes ).toContain( cause2 );
+    } );
+  } );
+
+  describe( 'type safety', () => {
+    it( 'should work with typed errors', () => {
+      const AppError = error<{ code: string }>( { name: 'AppError' } );
+      const ValidationError = error<{ field: string }>( { name: 'ValidationError' } );
+
+      const cause = AppError( { code: 'ERR001' } );
+      const instance = ValidationError( { field: 'email' } );
+
+      instance.from( cause );
+
+      expect( instance.cause ).toBe( cause );
+      expect( ( instance.cause as AppError ).fields.code ).toBe( 'ERR001' );
+    } );
+
+    it( 'should maintain instance fields after .from()', () => {
+      const ValidationError = error<{ field: string }>( {
+        name: 'ValidationError',
+        message: 'Field "{field}" is invalid',
+      } );
+
+      const instance = ValidationError( { field: 'email' } );
+      instance.from( new Error( 'network error' ) );
+
+      expect( instance.fields.field ).toBe( 'email' );
+      expect( instance.message ).toBe( 'Field "email" is invalid' );
+    } );
+  } );
+
+  describe( 'edge cases', () => {
+    it( 'should work with errors without causes property', () => {
+      const AppError = error( { name: 'AppError' } );
+      const instance = AppError();
+
+      // Native errors don't have causes property
+      instance.from( new Error( 'native' ) );
+
+      expect( instance.cause ).toBeInstanceOf( Error );
+      expect( instance.causes ).toHaveLength( 1 );
+    } );
+
+    it( 'should work with custom errors that have causes', () => {
+      const AppError = error( { name: 'AppError' } );
+      const ValidationError = error( { name: 'ValidationError' } );
+
+      const innerError = AppError();
+      innerError.from( new Error( 'inner cause' ) );
+
+      const outerError = ValidationError();
+      outerError.from( innerError );
+
+      expect( outerError.causes ).toHaveLength( 2 );
+      // Direct cause is innerError, then nativeError (from innerError's chain)
+      expect( outerError.cause ).toBe( innerError );
+      expect( outerError.causes ).toContain( innerError );
+      // The native error with 'inner cause' is in the causes chain
+      const nativeInCauses = outerError.causes.find( c => c.message === 'inner cause' );
+      expect( nativeInCauses ).toBeDefined();
+    } );
+  } );
+} );